Synthesis of Unsymmetrically Disubstituted Tetraphenylenes via Carbonyl-Directed C–H Functionalization

array(2) { ["lab"]=> string(3) "361" ["publication"]=> string(4) "4714" } Synthesis of Unsymmetrically Disubstituted Tetraphenylenes via Carbonyl-Directed C–H Functionalization - 张扬会课题组 | LabXing

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2016

期刊 Synlett

作者 Yanghui Zhang · Shulei Pan · Hang Jiang · Yu Zhang · Dushen Chen

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A new strategy for the synthesis of unsymmetrically disubstituted tetraphenylenes from 2-acetylbiphenylene has been developed via ruthenium-catalyzed C–H functionalization. Four reactions, including alkenylation–cyclization, alkenylation, alkylation, and amidation, were achieved. The reactions provide easy access to a variety of unsymmetrically disubstituted tetraphenylene derivatives, which could accelerate research on the appliation of tetraphenylenes.

卷 27
期 13
页码 1997-2002
Georg Thieme Verlag KG
ISSN: 0936-5214
DOI: 10.1055/s-0035-1561862

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