array(2) { ["lab"]=> string(3) "361" ["publication"]=> string(4) "4720" } Oxalic acid as the in situ carbon monoxide generator in palladium-catalyzed hydroxycarbonylation of arylhalides - 张扬会课题组 | LabXing

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大学 同济大学 / 化学科学与工程学院
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Oxalic acid as the in situ carbon monoxide generator in palladium-catalyzed hydroxycarbonylation of arylhalides

2017
期刊 Organic & Biomolecular Chemistry
An efficient palladium-catalyzed hydroxycarbonylation reaction of arylhalides using oxalic acid as a CO source has been developed. The reaction features high safety, low catalyst loading, and a broad substrate scope, and provides a safe and tractable approach to access a variety of aromatic carboxylic acid compounds. Mechanistic studies revealed the decomposition pattern of oxalic acid.

  • 卷 15
  • 期 23
  • 页码 5033-5040
  • Royal Society of Chemistry (RSC)
  • ISSN: 1477-0520
  • DOI: 10.1039/c7ob01052d
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