array(2) { ["lab"]=> string(3) "361" ["publication"]=> string(4) "4724" } Synthesis of 9,9-Disubstituted Fluorenes from 2-Iodobiphenyls and α-Diazoesters under Palladium Catalysis - 张扬会课题组 | LabXing

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大学 同济大学 / 化学科学与工程学院
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Synthesis of 9,9-Disubstituted Fluorenes from 2-Iodobiphenyls and α-Diazoesters under Palladium Catalysis

2018
期刊 The Journal of Organic Chemistry
9,9-Disubstituted fluorenes are widely employed in materials science. We have developed a straightforward approach for the synthesis of 9,9-disubstituted fluorenes from 2-iodobiphenyls and α-diazoesters. The reaction proceeds via a tandem palladium-catalyzed C(sp2)–H activation/carbenoid insertion sequence.

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