array(2) { ["lab"]=> string(3) "361" ["publication"]=> string(4) "4725" } Synthesis of Carbazoles from 2-Iodobiphenyls by Palladium-Catalyzed C−H Activation and Amination with Diaziridinone - 张扬会课题组 | LabXing

张扬会课题组

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大学 同济大学 / 化学科学与工程学院
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Synthesis of Carbazoles from 2-Iodobiphenyls by Palladium-Catalyzed C−H Activation and Amination with Diaziridinone

2017
期刊 Advanced Synthesis & Catalysis
A facile and efficient approach has been developed for the synthesis of carbazoles from 2‐iodobiphenyls and diaziridinone under palladium catalysis. A wide range of carbazoles were synthesized in good to excellent yields, and indole derivatives were obtained by using styrenes as the substrate. The palladacycles obtained from 2‐iodobiphenyls acted as the key intermediate, and the reaction should proceed via a tandem Pd‐catalyzed C−H activation/dual C−N bond formation sequence.

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